Know What You Wear: Materials in Your Closet (Part 1)

When was the last time you looked at the label on your clothes? Are you always aware of the fiber content of the pieces you buy, or do the fit, look, and price matter more to you? Recently, I did a deep dive into my closet and looked at all the labels. While materials like cotton, wool, or polyester are well-known, others like modal, lyocell, or rayon might leave us scratching our heads. So, let’s explore these materials and truly get to know what’s in your closet.

I’ve divided materials into these categories and subcategories:

  1. Man-Made (includes synthetics and semi-synthetic fibers)
  2. Natural (includes plant-based and animal-based fibers)

In this article, I’ll focus on the first category: Man-Made Fibers.


Key Synthetic Fibers

1. Polyester

Source: Polyethylene terephthalate (PET)

Polyester is one of the most common synthetic fibers in modern textiles. It has a complex and intriguing history that underscores both its versatility and its environmental impact. The production of polyester starts with the extraction of crude oil, which is then refined to produce ethylene glycol and terephthalic acid, the primary components of polyethylene terephthalate (PET).

Polyester became hugely popular in the 1950s and 1960s for its affordability and low maintenance. However, it fell out of favor in the 1970s due to its association with “leisure suits,” which became a symbol of bad taste for a generation. In the 1990s, advancements in technology led to the development of performance polyester with new cross-sections and geometries, such as Dri-FIT, which was first used in the U.S. Olympic uniforms in 1996. This marked a resurgence in polyester’s popularity, particularly in activewear.

While polyester offers benefits like wrinkle resistance, quick drying, and affordability, its environmental footprint is significant. The production process is energy-intensive, contributing to greenhouse gas emissions and relying on non-renewable petroleum resources. Moreover, polyester is not biodegradable and can take hundreds of years to decompose, leading to long-term pollution in landfills and oceans. The shedding of microfibers during washing further exacerbates environmental issues, as these tiny plastics harm marine life and contaminate water bodies.

2. Nylon

Source: Petrochemicals

Nylon, the world’s first commercially viable synthetic fiber, was invented in 1938 by a team of chemists at DuPont. It was initially marketed as a synthetic alternative to silk and first gained public attention at the 1939 World’s Fair. During World War II, nylon played a crucial role in the production of parachutes and other military equipment. Its earliest commercial use was in toothbrush bristles, followed by women’s stockings, which became an instant sensation. Today, nylon is used in a wide range of products, from sports apparel and equipment to ropes and industrial textiles, due to its exceptional strength, elasticity, and resistance to mildew.

Nylon’s versatility has led to its use in diverse products, including umbrellas, toilet brushes, guitar strings, and medical implants. Its ability to mold into various shapes and its resistance to chemicals and heat make it an indispensable material in modern manufacturing.

3. Acrylic

Source: Polyacrylonitrile

Acrylic fiber, also known as polyacrylonitrile (PAN), is a versatile synthetic material widely used in the textile industry. It is made by combining acrylonitrile with other chemicals to create a polymer, which is then spun into fibers using either wet or dry methods. Wet spinning involves forming fibers in a liquid bath, while dry spinning uses heat to evaporate solvents and shape the fibers. Once processed, acrylic fibers are resistant to UV light, chemicals, and biological agents, making them ideal for clothing, carpets, outdoor fabrics, and even as precursors for carbon fibers.

The unique properties of acrylic fibers, such as their softness, warmth, and lightweight nature, have made them a popular substitute for wool. Additionally, their ability to mimic the look and feel of natural fibers while offering easy care and affordability has cemented their place in modern textiles. Whether used in sweaters, hats, or home furnishings, acrylic fibers continue to play a significant role in the textile industry due to their versatility and continuous innovations in production processes.

4. Spandex (Lycra)

Source: Polyurethane

Lycra, commonly known as spandex or elastane, was invented in the early 1960s at DuPont’s Benger Laboratory. Initially called “Fiber K,” it was later branded as Lycra. This synthetic fiber revolutionized the textile industry with its exceptional elasticity, being able to stretch up to 500% of its original length and return to its original shape.

Lycra’s introduction in the 1960s transformed fashion, particularly in form-fitting and intimate apparel. It replaced rubber in girdles and pantyhose, making these garments more comfortable, lighter, and easier to care for. The rise of the miniskirt in the 1960s was also facilitated by Lycra, as it allowed for higher hemlines without the need for restrictive undergarments.

Lycra made its international athletic debut at the 1968 Winter Olympics in Grenoble, France, where the French men’s alpine ski team wore Lycra suits and dominated the medal count. This success led to its widespread adoption in various sports, including swimming, cycling, and track and field. Lycra’s use in sportswear enhances performance by providing a snug fit, reducing drag, and offering support and flexibility.

Beyond fashion and sportswear, Lycra is used in medical textiles such as compression stockings and bandages. Lycra became a household name in the 1990s with its “Nothing Moves like Lycra” campaign, which marked a significant shift in consumer awareness and trust in the brand. Celebrity endorsements, including Audrey Hepburn and other notable figures, further boosted its popularity. Overall, Lycra’s impact on the textile industry has been profound. Offering unmatched comfort, flexibility, and performance across a wide range of applications, from everyday wear to high-performance sportswear and medical textiles.


Key Semi-Synthetic Fibers

Semi-synthetic fibers like rayon, modal, and lyocell start with natural cellulose but undergo chemical processing to become fibers.

1. Rayon

Source: Wood pulp (including eucalyptus, beech, and bamboo)

The concept of rayon dates back to the 19th century, driven by the need to create an artificial substitute for silk. French inventor Hilaire de Chardonnet is often credited as the “father of the rayon industry” for his work in the 1880s.

Rayon is a semi-synthetic fiber made from regenerated cellulose, typically derived from wood pulp or cotton linters. The cellulose is dissolved in a chemical solution, extruded through a spinneret, and then coagulated in a bath to form fibers.

Rayon is known for its soft, silky texture and luxurious appearance, making it a popular choice for clothing and home textiles. It drapes well, has a smooth feel, and is highly absorbent (nearly twice as absorbent as cotton). This makes it ideal for summer clothing and bedding. Rayon is versatile and used in a variety of applications. In the textile industry, it is commonly used to make dresses, skirts, blouses, lingerie, and other apparel. It is also used in home furnishings such as sheets, curtains, blankets, and upholstery.

While rayon is made from natural cellulose, its production involves significant chemical processing, which can have environmental impacts. However, some types of rayon, such as Lyocell, are produced using more sustainable methods.

2. Viscose (First-Generation Rayon)

Source: Wood pulp

Viscose, often referred to as “artificial silk,” is a semi-synthetic fiber known for its softness, breathability, and affordability. Made primarily from wood pulp sources like eucalyptus, beech, and bamboo, its production involves several chemical processes, including alkali treatment and xanthation, to transform natural cellulose into a soluble form. The final fibers are regenerated through extrusion into a sulfuric acid bath, then washed, dried, and cut to the desired length. This intricate process gives viscose its luxurious feel and excellent drapability, making it a popular choice for clothing such as dresses, blouses, and linings, as well as home textiles like curtains and bed linens.

Viscose is prized for its versatility and ability to blend with other fibers like cotton, polyester, or spandex, enhancing its properties for various applications. It is highly breathable and moisture-absorbent, making it ideal for warm-weather garments. Additionally, its capacity to absorb dye results in vibrant, long-lasting colors. Despite its many advantages, viscose production has environmental drawbacks due to the use of toxic chemicals like carbon disulfide. However, more sustainable practices, such as closed-loop systems that recycle solvents, are being adopted by some manufacturers to reduce waste and environmental impact.

3. Modal (Second-Generation Rayon)

Source: Beech trees

Modal fabric is made from the pulp of beech trees, which are harvested, chipped into small pieces, and then purified to extract the cellulose content. After a few more steps, the solution solidifies into fibers. Unlike traditional viscose production, the modal process skips the aging step, resulting in a more efficient and less toxic process. Modal fabric is renowned for its soft, silky texture and excellent drape, making it comfortable against the skin and allowing it to hang gracefully. It also absorbs 50% more moisture than cotton, making it ideal for activewear, sportswear, and undergarments.

Despite its softness, modal is durable and resistant to wear and tear. It resists shrinking, pilling, and fading, making it suitable for long-lasting garments.

Modal is considered more eco-friendly than traditional viscose rayon due to its lower concentration of sodium hydroxide and the absence of the aging process, which reduces toxic waste. The beech trees used are often sourced from sustainably managed forests, and they require less water than cotton plants. Additionally, modal fibers are biodegradable, which is a significant environmental advantage compared to many synthetic fibers.

4. Lyocell (Third-Generation Rayon)

Source: Eucalyptus or other wood pulp

Lyocell is a semi-synthetic fiber made from regenerated cellulose, primarily derived from the wood pulp of eucalyptus trees. It was developed in the early 1970s at the American Enka fibers facility in North Carolina, where researchers sought a more environmentally friendly alternative to traditional rayon production methods, which often involve toxic chemicals like carbon disulfide. The process for producing lyocell was patented in the 1980s, and it was initially marketed under the brand name Tencel by Courtaulds Fibres. Today, Tencel is a well-recognized name in sustainable textiles, and Lenzing AG is the largest producer of lyocell fibers.

One of the most interesting aspects of lyocell is its environmentally friendly production process. Unlike other forms of rayon, lyocell is produced using a closed-loop system that recycles up to 99% of the solvents used, minimizing waste and reducing environmental impact. This method not only conserves resources but also results in fibers that are biodegradable and compostable. Lyocell fibers are known for their exceptional softness, breathability, and moisture-wicking properties, making them ideal for clothing and home textiles. They absorb moisture better than cotton and have a luxurious feel, often compared to silk, which has contributed to their popularity in high-end fashion and sustainable clothing lines.

5. Tencel (A Lyocell Brand)

Source: Eucalyptus and beech trees

Tencel is a trademarked form of lyocell by Lenzing AG. It’s made from the wood pulp of trees, primarily eucalyptus and beech trees, sourced from sustainably managed forests certified by the Forest Stewardship Council (FSC) and the Programme for the Endorsement of Forest Certification (PEFC).

Tencel requires less energy and water than conventional cotton production. It also uses fewer dyes than cotton, and no bleaching is necessary due to its natural white color. The global demand for Tencel is increasing, driven by consumer interest in sustainable and eco-friendly fabrics. Brands such as Levi’s, H&M, and Patagonia have incorporated Tencel into their collections, reflecting the growing trend toward sustainable fashion.

Summary of Semi-Synthetic Fibers:

  • Rayon: The main category of regenerated cellulose fibers.
    • Viscose Rayon: First generation, known for its high luster but less sustainable production process.
    • Modal: Second generation, made from beech tree cellulose, with enhanced softness and strength.
    • Lyocell: Third generation, produced using a closed-loop system with NMMO, highly sustainable and eco-friendly.
      • Tencel: A trademarked brand of lyocell fibers produced by Lenzing AG, representing the highest quality and sustainability within the lyocell category.

Conclusion


Understanding what’s in your clothes is the first step toward mindful consumption. While man-made fibers offer many benefits, it’s essential to consider their environmental impact. In the Part 2 of this series, we’ll explore natural fibers and their role in sustainable fashion. Stay tuned!

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Vanda
Vanda

I started this blog as a way to give my random notes, thoughts, research, and saved resources a place to live and take shape. It’s my personal space to revisit and reflect, and even better if others find the information helpful and inspiring along the way.